1.4104 is a free-machining martensitic stainless steel containing about 17% chromium with sulphur and a small molybdenum addition. This datasheet presents the material within the Werkstoff-Nummer (DIN / EN) designation system.
With nominally 17% chromium, added sulphur and a small molybdenum content, 1.4105 is essentially the free-machining version of 1.4016 (X6Cr17): the sulphur forms manganese-sulphide inclusions that improve chip breaking and machinability, while the molybdenum partly offsets the resulting loss of corrosion resistance. Being a low-carbon ferritic grade it is magnetic and cannot be hardened by heat treatment, and offers properties similar to 1.4016 with markedly better machinability. It is widely used for automatic-lathe production of small turned parts.
Typical applications include screws, nuts, fasteners, toolholders, ball valves, fittings, furniture parts, and components for the petrochemical, automotive, food and machinery industries.
Typical values, annealed condition, per EN reference data.
| Property | Value | Unit |
|---|---|---|
| Density | 7.7 | g/cm³ |
| Melting range | 1425–1510 | °C |
| Elastic modulus | 220 | GPa |
| Coefficient of thermal expansion (20–100 °C) | 10.0 | µm/m·°C |
| Thermal conductivity (20 °C) | 25.0 | W/m·K |
| Specific heat (20 °C) | 460 | J/kg·K |
| Structure | Martensitic (free-machining) | — |
Specified per EN 10088-3 (W.Nr. 1.4104, X14CrMoS17).
| Element | Symbol | Min % | Max % | Role in Alloy |
|---|---|---|---|---|
| Iron | Fe | Balance | — | Base element |
| Chromium | Cr | 16.0 | 18.0 | Corrosion resistance |
| Sulphur | S | 0.15 | 0.35 | Free-machining (MnS inclusions) |
| Molybdenum | Mo | 0.20 | 0.60 | Offsets sulphur loss of corrosion resistance |
| Manganese | Mn | — | 1.50 | Forms MnS; deoxidiser |
| Silicon | Si | — | 1.50 | Deoxidiser |
| Carbon | C | 0.10 | 0.17 | Higher (heat-treatable) |
| Phosphorus | P | — | 0.040 | Residual impurity |
Nominal: 17Cr free-machining (sulphurised) martensitic stainless steel; higher carbon.
Annealed (+A) condition, per EN 10088-3 for W.Nr. 1.4105.
| Condition | Property | Value |
|---|---|---|
| Annealed | Tensile strength (Rm) | 500–700 MPa |
| Annealed | 0.2% proof strength (Rp0.2) | ≥300 MPa |
| Annealed | Elongation (A5) | ≥15 % |
| Quenched & tempered (+QT) | Tensile strength (Rm) | 650–850 MPa |
| Quenched & tempered (+QT) | Hardness | ~220–280 HB |
Values per EN 10088-3; the higher carbon permits hardening and tempering. Confirm against the inspection certificate (EN 10204).
| Environment | Performance | Notes |
|---|---|---|
| Atmospheric / general | Moderate | Below 1.4016 (sulphur reduces resistance) |
| Organic and nitric acids | Good | At low concentrations |
| Chloride pitting / crevice | Limited | Sulphide inclusions are initiation sites |
| Chloride stress-corrosion cracking | Very Good | Ferritic — largely immune |
| Seawater | Not recommended | — |
Corrosion resistance is moderate and below 1.4016; not resistant to intergranular corrosion. The molybdenum addition partly offsets the loss caused by the sulphur.
A free-machining grade classified by EN as martensitic; the higher carbon allows limited hardening by heat treatment.
Anneal Heat to approximately 760–820 °C and cool slowly for the soft, machinable condition.
Harden and Temper (+QT) The higher carbon allows hardening from ~980–1040 °C (oil or air quench) followed by tempering at 600–750 °C to develop higher strength. Avoid tempering in the 400–540 °C range (475 °C embrittlement).
Not suitable for welding — the high sulphur content promotes hot cracking.
| Welding Process | Applicability | Filler / Consumable |
|---|---|---|
| GTAW / TIG | Not recommended | Austenitic (309) if unavoidable |
| GMAW / MIG | Not recommended | — |
| Brazing | Preferred join method | — |
The free-machining sulphur addition makes this grade unsuitable for structural welding.
Machining Guidelines
| Parameter | Recommendation |
|---|---|
| Machinability | Excellent — designed for automatic lathes |
| Chip breaking | MnS inclusions break chips; high speeds and feeds possible |
| Tooling | Standard carbide or HSS; good tool life |
| Coolant | Ample flood coolant |
Forming Processes
| Process | Notes |
|---|---|
| Cold forming | Limited — sulphur reduces ductility |
| Hot forming | ~1130–1050 °C forging range; anneal afterward |
| Industry | Typical Components | Key Requirements |
|---|---|---|
| Screw machining | Screws, nuts, fasteners, turned parts | Extensive machining |
| Petrochemical | Toolholders, fittings, valve parts | Machinability + moderate corrosion resistance |
| Food / machinery | Ball valves, machine parts | Machinability + corrosion resistance |
| Furniture / appliances | Decorative and functional parts | Machinability + cost |
| Product Form | DIN / EN Standard | Notes |
|---|---|---|
| Bar, rod and sections | EN 10088-3 · W.Nr. 1.4105 | X6CrMoS17 |
| Wire | EN 10088-3 · W.Nr. 1.4105 | — |
| Forging stock | EN 10088-3 · W.Nr. 1.4105 | — |
| Technical delivery | SEW 400 | — |
Free-machining (sulphurised) ferritic stainless steel. W.Nr. 1.4104 (X14CrMoS17).
| W.Nr. | Cr % | S % | Mo % | Best Used For |
|---|---|---|---|---|
| 1.4104 | 16–18 | 0.15–0.35 | 0.2–0.6 | Free-machining (martensitic, heat-treatable); screw-machine parts |
| 1.4016 | 16–18 | ≤0.015 | — | General ferritic; non-free-machining |
| 1.4105 | 16–18 | 0.15–0.35 | 0.2–0.6 | Free-machining ferritic (lower carbon) |
| 1.4005 | 12–14 | 0.15–0.35 | ≤0.60 | Free-machining martensitic |
| 1.4305 | 17–19 | 0.15–0.35 | — | Free-machining austenitic |




